Use the already known instrument to create the eyelids with the color 681525:

Drawing Illustration with Woman in Photoshop

Use the same instrument to draw the eye pupils of black color:

Drawing Illustration with Woman in Photoshop

The same instrument will help us to hide a part of the right eye under the hat. The white color:

Drawing Illustration with Woman in Photoshop

The instrument EllipseTool will help to create circle with the parameters demonstrated in the picture:

Drawing Illustration with Woman in Photoshop

Stroke:
  


Drawing Illustration with Woman in Photoshop

Fill 0% in the layers
Use the instrument PenTool to dark out the girl's hat, making use of the following parameters:

Drawing Illustration with Woman in Photoshop

Gradient Overlay:

Drawing Illustration with Woman in Photoshop

Gradient's parameters:

Drawing Illustration with Woman in Photoshop

Fill 0% in the layers.
The last feature consists of adding the eyebrow of black color by the eye:

Drawing Illustration with Woman in Photoshop

The final result!