Now I'm going to add some additional shadows to my image. Create a layer and name it shadows.  



Use these brush settings.  



Add shadows to the arm.  



 



And the face.  



Create a layer. On this layer and don't even why but I want to create some kind of face mask or just change the color of the lower part of the face.  



 



Warp a little bit.  



Change the layer mode to Soft light.  



Now we'll deal with hair a little bit. Create another layer, name it HAIR  



Use the brush with these settings.  



Pick orange or something like orange color and begin.  



 



 



Now the final steps.

Use the same brush with the same overlay settings. And paint on the Hands area  



 



Overall.  



In the end I would like to use Exposure filter in Adjustments section.  



AAAnd we are done with this angel. Details:  



 



 



Hope you found out some new techniques here and follow me in my next tutorials.

 



I think there will be more on character design and some other Digital concept art techniques.